Don't worry about encompassing the whole audience with FL and FR, the centre channel is for that, it will make a difference, but way smaller than the treble does at the moment.
equilateral triangle toe'd in to the listening posi... well it means that they have to be equally far from the one centre listening position, and point more or less to that position... there's a lot of scope to play in there. Their imaginary forward lines can cross at, behind, or in front of the centre position. If you are worried about not giving everybody sound, I suggest move it as mentioned previously and let the speakers cross 20cm in front of centre listening position's nose.
Honestly if Polk advises you to play them right at the listening position, they shouldn't be that bright. I do believe it is your room, and unless the Jamo's have a much different radiation pattern, I think the change will be small. Ja Jamo's are often less "bright", don't know the modern models... This is where your specialist retailer should come and visit you and look at the room for no charge and make suggestions re speaker placement and / or substitution... You dropped quite a bit of money on this set-up and they need to look after their customers... I think they would be glad to help in all honesty - as issues like these on the internet give their products a bit of a name...
In my previous listening room I had the same issue until I absorbed the first reflection points, and nailed the flutter echo's, and all of a sudden all of the issues I had with adjusting my X-O was gone, and I could dial my tweeter up to where theoretically it made sense.